Technical Comparison: Peroxide vs. Platinum Cure Systems for Silicone Rubber

ntroduction
Silicone vulcanization transforms raw polymers into elastic networks through crosslinking. TN Silicone offers two dominant systems: Peroxide (Di-Cup 2,5) and Platinum Catalysts. Understanding their distinctions is critical for optimal material selection.

Key Comparison

ParameterPeroxide (Di-Cup 2,5) CurePlatinum Cure
Curing MechanismFree-radical crosslinkingAddition reaction (Hydrosilylation)
ByproductsVolatile organic compounds (VOCs) possibleNone; non-polluting reaction
Cure SpeedModerate to fast; requires T° controlSlower initiation, precise cure kinetics
Typical Cure TemperatureHigher (150°C–180°C)Lower (100°C–150°C); energy-efficient
Transparency & ColorSlight yellowing possibleExcellent clarity; optical-grade
Heat ResistanceExcellent long-term stability (>200°C)Good (up to 180°–200°C)
Chemical ResistanceBroad compatibilitySuperior against polar solvents
BiocompatibilityLimitedExceptional; ideal for medical/food
Regulatory ComplianceIndustrial standards (RoHS, REACH)FDA, EU 10/2011, ISO 10993, USP Class VI
Cost EfficiencyLower raw material costHigher catalyst cost

TN Silicone’s Competitive Advantages

  1. Peroxide Systems (Di-Cup 2,5):
    • Optimized Formulations: Minimize VOC emissions vs. conventional peroxides.
    • Enhanced Thermal Stability: Withstands extended high-temp exposure (tested to 250°C).
    • Cost-Performance Leader: Ideal for automotive, industrial seals, and electrical insulation.
  2. Platinum Systems:
    • Ultra-High Purity Catalysts: Meet ISO 13485 for medical devices and food-contact applications.
    • Low-Inhibition Technology: Tolerant to common manufacturing contaminants (e.g., Sn, S).
    • Eco-Certified: Zero VOCs, supporting sustainable manufacturing.

Why TN Silicone?

  • R&D Expertise: Customizable cure profiles for complex applications.
  • Global Compliance: Full traceability and documentation (REACH, TSCA, K-REACH).
  • Technical Support: Lab-to-production scale-up assistance.

Conclusion
Select peroxide for cost-driven, high-heat industrial uses; choose platinum for purity-critical applications. TN Silicone guarantees performance, compliance, and supply-chain reliability.

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